Of course, it could have been at any time, but I'm inclined to think that it was after the Master was trapped in the '30s. I can't imagine the Master going to the wilds of California much before the prophesied time to open the Hellmouth, which would have been in the 30's, but I like the idea of Darla coming later, and trying vainly to free him for a few decades. I've got fic!
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So, what did she do in the meantime? Was she with Spike and Dru? By herself? With the Master?